Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

Melinda J. Duer; Muhammad S. Khan; Ashok K. Kakkar

doi:10.1016/0926-2040(92)90005-T

Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PⁿBu₃)₂CCpC₆H₄CCPt(PⁿBu₃)₂Cl] and trans-[Pt(PⁿBu₃)₂CCpC₆H₄CC]_n

Melinda J. Duer^*, Muhammad S. Khan, Ashok K. Kakkar

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Solid state ¹³C, ³¹P and ¹⁹⁵Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PⁿBu₃)₂CCpC₆H₄CCPt(PⁿBu₃)₂Cl] and trans-[Pt(PⁿBu₃)₂CCpC₆H₄CC]_n. The ¹⁹⁵Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

Original language	English
Pages (from-to)	13-16
Number of pages	4
Journal	Solid State Nuclear Magnetic Resonance
Volume	1
Issue number	1
DOIs	https://doi.org/10.1016/0926-2040(92)90005-T
Publication status	Published - Feb 1992
Externally published	Yes

Keywords

acetylide
phosphorous
platinum
polymer
shielding tensor

ASJC Scopus subject areas

Radiation
Chemistry(all)
Nuclear and High Energy Physics
Instrumentation

Access to Document

10.1016/0926-2040(92)90005-T

Cite this

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title = "Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n",

abstract = "Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.",

keywords = "acetylide, phosphorous, platinum, polymer, shielding tensor",

author = "Duer, {Melinda J.} and Khan, {Muhammad S.} and Kakkar, {Ashok K.}",

year = "1992",

month = feb,

doi = "10.1016/0926-2040(92)90005-T",

language = "English",

volume = "1",

pages = "13--16",

journal = "Solid State Nuclear Magnetic Resonance",

issn = "0926-2040",

publisher = "Elsevier",

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TY - JOUR

T1 - Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

AU - Duer, Melinda J.

AU - Khan, Muhammad S.

AU - Kakkar, Ashok K.

PY - 1992/2

Y1 - 1992/2

N2 - Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

AB - Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

KW - acetylide

KW - phosphorous

KW - platinum

KW - polymer

KW - shielding tensor

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