Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

Melinda J. Duer; Muhammad S. Khan; Ashok K. Kakkar

doi:10.1016/0926-2040(92)90005-T

Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PⁿBu₃)₂CCpC₆H₄CCPt(PⁿBu₃)₂Cl] and trans-[Pt(PⁿBu₃)₂CCpC₆H₄CC]_n

Melinda J. Duer^*, Muhammad S. Khan, Ashok K. Kakkar

^*المؤلف المقابل لهذا العمل

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

15 اقتباسات (Scopus)

ملخص

Solid state ¹³C, ³¹P and ¹⁹⁵Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PⁿBu₃)₂CCpC₆H₄CCPt(PⁿBu₃)₂Cl] and trans-[Pt(PⁿBu₃)₂CCpC₆H₄CC]_n. The ¹⁹⁵Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

اللغة الأصلية	English
الصفحات (من إلى)	13-16
عدد الصفحات	4
دورية	Solid State Nuclear Magnetic Resonance
مستوى الصوت	1
رقم الإصدار	1
المعرِّفات الرقمية للأشياء	https://doi.org/10.1016/0926-2040(92)90005-T
حالة النشر	Published - فبراير 1992
منشور خارجيًا	نعم

ASJC Scopus subject areas

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الوصول إلى المستند

10.1016/0926-2040(92)90005-T

الملفات والروابط الأخرى

قم بذكر هذا

Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PⁿBu₃)₂CCpC₆H₄CCPt(PⁿBu₃)₂Cl] and trans-[Pt(PⁿBu₃)₂CCpC₆H₄CC]_n. / Duer, Melinda J.; Khan, Muhammad S.; Kakkar, Ashok K.
في: Solid State Nuclear Magnetic Resonance, المجلد 1, رقم 1, ٠٢.١٩٩٢, صفحة 13-16.

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

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abstract = "Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.",

keywords = "acetylide, phosphorous, platinum, polymer, shielding tensor",

author = "Duer, {Melinda J.} and Khan, {Muhammad S.} and Kakkar, {Ashok K.}",

year = "1992",

month = feb,

doi = "10.1016/0926-2040(92)90005-T",

language = "English",

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T1 - Solid state multinuclear NMR study of σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n

AU - Duer, Melinda J.

AU - Khan, Muhammad S.

AU - Kakkar, Ashok K.

PY - 1992/2

Y1 - 1992/2

N2 - Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

AB - Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric σ-acetylide complexes of platinum, trans-[ClPt(PnBu3)2CCpC6H4CCPt(PnBu3)2Cl] and trans-[Pt(PnBu3)2CCpC6H4CC]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds.

KW - acetylide

KW - phosphorous

KW - platinum

KW - polymer

KW - shielding tensor

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JO - Solid State Nuclear Magnetic Resonance

JF - Solid State Nuclear Magnetic Resonance

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