Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

Richard Frantz; Christopher S. Grange; Nawal K. Al-Rasbi; Michael D. Ward; Jérôme Lacour

doi:10.1039/b618092b

Enantiodifferentiation of chiral cationic cages using trapped achiral BF₄^- anions as chirotopic probes

Richard Frantz, Christopher S. Grange, Nawal K. Al-Rasbi, Michael D. Ward^*, Jérôme Lacour

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co₄(L)₆(BF₄)]⁷⁺ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

Original language	English
Pages (from-to)	1459-1461
Number of pages	3
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b618092b
Publication status	Published - 2007
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes",

abstract = "The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co4(L)6(BF4)]7+ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.",

author = "Richard Frantz and Grange, {Christopher S.} and Al-Rasbi, {Nawal K.} and Ward, {Michael D.} and J{\'e}r{\^o}me Lacour",

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AU - Frantz, Richard

AU - Grange, Christopher S.

AU - Al-Rasbi, Nawal K.

AU - Ward, Michael D.

AU - Lacour, Jérôme

PY - 2007

Y1 - 2007

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AB - The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co4(L)6(BF4)]7+ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

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DO - 10.1039/b618092b

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Enantiodifferentiation of chiral cationic cages using trapped achiral BF₄^- anions as chirotopic probes

Abstract

ASJC Scopus subject areas

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