Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

Richard Frantz; Christopher S. Grange; Nawal K. Al-Rasbi; Michael D. Ward; Jérôme Lacour

doi:10.1039/b618092b

Enantiodifferentiation of chiral cationic cages using trapped achiral BF₄^- anions as chirotopic probes

Richard Frantz, Christopher S. Grange, Nawal K. Al-Rasbi, Michael D. Ward^*, Jérôme Lacour

^*المؤلف المقابل لهذا العمل

نتاج البحث: المساهمة في مجلة › Article › مراجعة النظراء

47 اقتباسات (Scopus)

ملخص

The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co₄(L)₆(BF₄)]⁷⁺ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

اللغة الأصلية	English
الصفحات (من إلى)	1459-1461
عدد الصفحات	3
دورية	Chemical Communications
رقم الإصدار	14
المعرِّفات الرقمية للأشياء	https://doi.org/10.1039/b618092b
حالة النشر	Published - 2007
منشور خارجيًا	نعم

ASJC Scopus subject areas

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الوصول إلى المستند

10.1039/b618092b

الملفات والروابط الأخرى

قم بذكر هذا

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title = "Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes",

abstract = "The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co4(L)6(BF4)]7+ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.",

author = "Richard Frantz and Grange, {Christopher S.} and Al-Rasbi, {Nawal K.} and Ward, {Michael D.} and J{\'e}r{\^o}me Lacour",

year = "2007",

doi = "10.1039/b618092b",

language = "English",

pages = "1459--1461",

journal = "Chemical Communications",

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T1 - Enantiodifferentiation of chiral cationic cages using trapped achiral BF4- anions as chirotopic probes

AU - Frantz, Richard

AU - Grange, Christopher S.

AU - Al-Rasbi, Nawal K.

AU - Ward, Michael D.

AU - Lacour, Jérôme

PY - 2007

Y1 - 2007

N2 - The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co4(L)6(BF4)]7+ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

AB - The addition of enantiopure TRISPHAT anions to chiral cationic cages of type [Co4(L)6(BF4)]7+ leads to the enantiodifferentiation of the ligands of the racemic salts and, even more effectively, of the achiral tetrafluoroborate anion trapped inside.

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