Abstract
The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.
Original language | English |
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Article number | st-2015-b0256-l |
Pages (from-to) | 1852-1856 |
Number of pages | 5 |
Journal | Synlett |
Volume | 26 |
Issue number | 13 |
DOIs | |
Publication status | Published - Aug 12 2015 |
Keywords
- aldol reaction
- hydrostannation
- natural products
- rearrangement
- total synthesis
ASJC Scopus subject areas
- Organic Chemistry