Synthesis of rod-like CeO2 nanoparticles and their application to catalyze the luminal–O2 chemiluminescence reaction used in the determination of oxcarbazepine and ascorbic acid

Mortaza Iranifam; Asghar Haggi; Hossein Akhteh; Mojtaba Amini; Haider A.J. Al Lawati

doi:10.1007/s44211-022-00096-5

Synthesis of rod-like CeO₂ nanoparticles and their application to catalyze the luminal–O₂ chemiluminescence reaction used in the determination of oxcarbazepine and ascorbic acid

Mortaza Iranifam^*, Asghar Haggi, Hossein Akhteh, Mojtaba Amini, Haider A.J. Al Lawati

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Abstract: Rod-like CeO₂ nanoparticles (NPs) were produced by the quick precipitation approach and employed as a catalyzer to increase the chemiluminescence (CL) intensity of the luminol–O₂ reaction. The transmission electron microscopy (TEM) images of the CeO₂ NPs showed that rod-like particles with the length and diameter about 15 nm and 5 nm, respectively, were produced. Furthermore, pharmaceuticals including oxcarbazepine (OXP) and ascorbic acid (AA) showed an inhibitory effect against the CL intensity such that the more concentration of the pharmaceuticals, the less was the CL intensity. Therefore, the new CeO₂ NPs–luminol–O₂ CL reaction was developed to determine OXP and AA in the pharmaceutical formulations. It is the first CL method established for the quantification of OXP. The linear dynamic range of this method for OXP was from 6.0 × 10^–7 to 6.0 × 10^–5 mol L⁻¹ and for AA from 1.0 × 10^–6 to 1.0 × 10^–4 mol L⁻¹. Graphical Abstract: [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	787-793
Number of pages	7
Journal	Analytical Sciences
Volume	38
Issue number	5
DOIs	https://doi.org/10.1007/s44211-022-00096-5
Publication status	Published - May 2022
Externally published	Yes

Keywords

Ascorbic acid
CeO nanoparticles
Chemiluminescence
Luminol
Oxcarbazepine

ASJC Scopus subject areas

Analytical Chemistry

Access to Document

10.1007/s44211-022-00096-5

Cite this

@article{d3a98feba154405c9838607c17099e24,

title = "Synthesis of rod-like CeO2 nanoparticles and their application to catalyze the luminal–O2 chemiluminescence reaction used in the determination of oxcarbazepine and ascorbic acid",

abstract = "Abstract: Rod-like CeO2 nanoparticles (NPs) were produced by the quick precipitation approach and employed as a catalyzer to increase the chemiluminescence (CL) intensity of the luminol–O2 reaction. The transmission electron microscopy (TEM) images of the CeO2 NPs showed that rod-like particles with the length and diameter about 15 nm and 5 nm, respectively, were produced. Furthermore, pharmaceuticals including oxcarbazepine (OXP) and ascorbic acid (AA) showed an inhibitory effect against the CL intensity such that the more concentration of the pharmaceuticals, the less was the CL intensity. Therefore, the new CeO2 NPs–luminol–O2 CL reaction was developed to determine OXP and AA in the pharmaceutical formulations. It is the first CL method established for the quantification of OXP. The linear dynamic range of this method for OXP was from 6.0 × 10–7 to 6.0 × 10–5 mol L−1 and for AA from 1.0 × 10–6 to 1.0 × 10–4 mol L−1. Graphical Abstract: [Figure not available: see fulltext.]",

keywords = "Ascorbic acid, CeO nanoparticles, Chemiluminescence, Luminol, Oxcarbazepine",

author = "Mortaza Iranifam and Asghar Haggi and Hossein Akhteh and Mojtaba Amini and {Al Lawati}, {Haider A.J.}",

note = "Funding Information: The authors thank the University of Maragheh (Maragheh, Iran) for all the support provided. We wish to acknowledge the Management of Research and Technology and the Central Laboratory of University of Maragheh for their help in running the experiments. Mortaza Iranifam would like to thank Ms. Iman Al-Lawati from Sultan Qaboos University, Sultanate of Oman, for help in taking TEM images. Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry.",

year = "2022",

month = may,

doi = "10.1007/s44211-022-00096-5",

language = "English",

volume = "38",

pages = "787--793",

journal = "Analytical Sciences",

issn = "0910-6340",

publisher = "Japan Society for Analytical Chemistry",

number = "5",

}

TY - JOUR

T1 - Synthesis of rod-like CeO2 nanoparticles and their application to catalyze the luminal–O2 chemiluminescence reaction used in the determination of oxcarbazepine and ascorbic acid

AU - Iranifam, Mortaza

AU - Haggi, Asghar

AU - Akhteh, Hossein

AU - Amini, Mojtaba

AU - Al Lawati, Haider A.J.

N1 - Funding Information: The authors thank the University of Maragheh (Maragheh, Iran) for all the support provided. We wish to acknowledge the Management of Research and Technology and the Central Laboratory of University of Maragheh for their help in running the experiments. Mortaza Iranifam would like to thank Ms. Iman Al-Lawati from Sultan Qaboos University, Sultanate of Oman, for help in taking TEM images. Publisher Copyright: © 2022, The Author(s), under exclusive licence to The Japan Society for Analytical Chemistry.

PY - 2022/5

Y1 - 2022/5

N2 - Abstract: Rod-like CeO2 nanoparticles (NPs) were produced by the quick precipitation approach and employed as a catalyzer to increase the chemiluminescence (CL) intensity of the luminol–O2 reaction. The transmission electron microscopy (TEM) images of the CeO2 NPs showed that rod-like particles with the length and diameter about 15 nm and 5 nm, respectively, were produced. Furthermore, pharmaceuticals including oxcarbazepine (OXP) and ascorbic acid (AA) showed an inhibitory effect against the CL intensity such that the more concentration of the pharmaceuticals, the less was the CL intensity. Therefore, the new CeO2 NPs–luminol–O2 CL reaction was developed to determine OXP and AA in the pharmaceutical formulations. It is the first CL method established for the quantification of OXP. The linear dynamic range of this method for OXP was from 6.0 × 10–7 to 6.0 × 10–5 mol L−1 and for AA from 1.0 × 10–6 to 1.0 × 10–4 mol L−1. Graphical Abstract: [Figure not available: see fulltext.]

AB - Abstract: Rod-like CeO2 nanoparticles (NPs) were produced by the quick precipitation approach and employed as a catalyzer to increase the chemiluminescence (CL) intensity of the luminol–O2 reaction. The transmission electron microscopy (TEM) images of the CeO2 NPs showed that rod-like particles with the length and diameter about 15 nm and 5 nm, respectively, were produced. Furthermore, pharmaceuticals including oxcarbazepine (OXP) and ascorbic acid (AA) showed an inhibitory effect against the CL intensity such that the more concentration of the pharmaceuticals, the less was the CL intensity. Therefore, the new CeO2 NPs–luminol–O2 CL reaction was developed to determine OXP and AA in the pharmaceutical formulations. It is the first CL method established for the quantification of OXP. The linear dynamic range of this method for OXP was from 6.0 × 10–7 to 6.0 × 10–5 mol L−1 and for AA from 1.0 × 10–6 to 1.0 × 10–4 mol L−1. Graphical Abstract: [Figure not available: see fulltext.]

KW - Ascorbic acid

KW - CeO nanoparticles

KW - Chemiluminescence

KW - Luminol

KW - Oxcarbazepine

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DO - 10.1007/s44211-022-00096-5

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C2 - 35298793

AN - SCOPUS:85129781743

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VL - 38

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EP - 793

JO - Analytical Sciences

JF - Analytical Sciences

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