TY - JOUR
T1 - Rise of conjugated poly-ynes and Poly(Metalla-ynes)
T2 - From design through synthesis to structure-property relationships and applications
AU - Haque, Ashanul
AU - Al-Balushi, Rayya A.
AU - Al-Busaidi, Idris Juma
AU - Khan, Muhammad S.
AU - Raithby, Paul R.
N1 - Funding Information:
Ashanul Haque completed his B.Sc. in Chemistry (2006) from Jamia Millia Islamia, India, and M.Sc. in Chemistry (2008) from Jamia Hamdard, India. He obtained his Ph.D. in Chemistry from Jamia Millia Islamia, India (2014) under the supervision of Prof. Imran Ali and Prof. Kishwar Saleem. During his Ph.D., he was the recipient of two major national research fellowships: Basic Science Junior Research Fellowship for meritorious students (BSR-JRF) and Senior Research Fellowship (SRF) in Organic Chemistry awarded by the University Grant’s Commission (UGC) and Council of Scientific and Industrial Research (CSIR), New Delhi, India, respectively. Since September 2014, he has been working as a postdoctoral fellow with Prof. Muhammad S. Khan at Sultan Qaboos University, Oman. His present research interests are centered on design and development of organic and organometallic compounds for biological and optoelectronics applications. Dr. Haque has an h-index of 13, an i10-index of 14 and 596 citations for his 39 published papers.
Funding Information:
The literature review leading to this review article was conducted with funding from His Majesty’s Trust Fund for Strategic Research (SR/SCI/CHEM/16/02). A.H. acknowledges The Research Council, Oman TRC for a Postdoctoral fellowship. R.A.B. acknowledges TRC for a Research Assistantship and SQU for a Ph.D. scholarship. I.J.A.B. acknowledges the Ministry of Education, Oman, for a Ph.D. scholarship. P.R.R. is grateful to the EPSRC for continued funding (EP/ K004956/1).
Publisher Copyright:
© Copyright 2018 American Chemical Society.
PY - 2018/9/26
Y1 - 2018/9/26
N2 - Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their intriguing and tunable chemical and photophysical properties. This review highlights fascinating advances made in the field of conjugated organic poly-ynes and poly(metalla-ynes) incorporating group 4-11 metals. This includes several important aspects of conjugated poly-ynes viz. synthetic protocols, bonding, electronic structure, nature of luminescence, structure-property relationships, diverse applications, and concluding remarks. Furthermore, we delineated the future directions and challenges in this particular area of research.
AB - Conjugated poly-ynes and poly(metalla-ynes) constitute an important class of new materials with potential application in various domains of science. The key factors responsible for the diverse usage of these materials is their intriguing and tunable chemical and photophysical properties. This review highlights fascinating advances made in the field of conjugated organic poly-ynes and poly(metalla-ynes) incorporating group 4-11 metals. This includes several important aspects of conjugated poly-ynes viz. synthetic protocols, bonding, electronic structure, nature of luminescence, structure-property relationships, diverse applications, and concluding remarks. Furthermore, we delineated the future directions and challenges in this particular area of research.
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U2 - 10.1021/acs.chemrev.8b00022
DO - 10.1021/acs.chemrev.8b00022
M3 - Review article
C2 - 30112905
AN - SCOPUS:85053703926
SN - 0009-2665
VL - 118
SP - 8474
EP - 8597
JO - Chemical Reviews
JF - Chemical Reviews
IS - 18
ER -