Probing interactions bymeans of pulsed field gradient nuclear magnetic resonance spectroscopy

Sara Cozzolino; Maria G. Sanna; Massimiliano Valentini

doi:10.1002/mrc.2345

Probing interactions bymeans of pulsed field gradient nuclear magnetic resonance spectroscopy

Sara Cozzolino, Maria G. Sanna, Massimiliano Valentini^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

11 Citations (Scopus)

Abstract

Molecular self-diffusion coefficients (D) of species in solution are related to size and shape and can be used for studying association phenomena. Pulsed field gradient nuclear magnetic resonance (PFG-NMR) spectroscopy has been revealed to be a powerful analytical tool for D measurement in different research fields. The present work briefly illustrates the use of PFG-NMR for assessing the existence of interactions in very different chemical systems: organic and organometallic compounds, colloidal materials and biological aggregates. The application of PFG-NMR is remarkable for understanding the role of anions in homogenous transition metal catalysis and for assessing the aggregation behaviour of biopolymers in material science.

Original language	English
Pages (from-to)	S16-S23
Journal	Magnetic Resonance in Chemistry
Volume	46
Issue number	SUPPL. 1
DOIs	https://doi.org/10.1002/mrc.2345
Publication status	Published - 2008
Externally published	Yes

Keywords

Colloidal aggregates
Diffusion coefficient
H
H-bonding
Interactions
PFG-NMR

ASJC Scopus subject areas

General Chemistry
General Materials Science

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10.1002/mrc.2345

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title = "Probing interactions bymeans of pulsed field gradient nuclear magnetic resonance spectroscopy",

abstract = "Molecular self-diffusion coefficients (D) of species in solution are related to size and shape and can be used for studying association phenomena. Pulsed field gradient nuclear magnetic resonance (PFG-NMR) spectroscopy has been revealed to be a powerful analytical tool for D measurement in different research fields. The present work briefly illustrates the use of PFG-NMR for assessing the existence of interactions in very different chemical systems: organic and organometallic compounds, colloidal materials and biological aggregates. The application of PFG-NMR is remarkable for understanding the role of anions in homogenous transition metal catalysis and for assessing the aggregation behaviour of biopolymers in material science.",

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T1 - Probing interactions bymeans of pulsed field gradient nuclear magnetic resonance spectroscopy

AU - Cozzolino, Sara

AU - Sanna, Maria G.

AU - Valentini, Massimiliano

PY - 2008

Y1 - 2008

N2 - Molecular self-diffusion coefficients (D) of species in solution are related to size and shape and can be used for studying association phenomena. Pulsed field gradient nuclear magnetic resonance (PFG-NMR) spectroscopy has been revealed to be a powerful analytical tool for D measurement in different research fields. The present work briefly illustrates the use of PFG-NMR for assessing the existence of interactions in very different chemical systems: organic and organometallic compounds, colloidal materials and biological aggregates. The application of PFG-NMR is remarkable for understanding the role of anions in homogenous transition metal catalysis and for assessing the aggregation behaviour of biopolymers in material science.

AB - Molecular self-diffusion coefficients (D) of species in solution are related to size and shape and can be used for studying association phenomena. Pulsed field gradient nuclear magnetic resonance (PFG-NMR) spectroscopy has been revealed to be a powerful analytical tool for D measurement in different research fields. The present work briefly illustrates the use of PFG-NMR for assessing the existence of interactions in very different chemical systems: organic and organometallic compounds, colloidal materials and biological aggregates. The application of PFG-NMR is remarkable for understanding the role of anions in homogenous transition metal catalysis and for assessing the aggregation behaviour of biopolymers in material science.

KW - Colloidal aggregates

KW - Diffusion coefficient

KW - H

KW - H-bonding

KW - Interactions

KW - PFG-NMR

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DO - 10.1002/mrc.2345

M3 - Review article

C2 - 18855336

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VL - 46

SP - S16-S23

JO - Magnetic Resonance in Chemistry

JF - Magnetic Resonance in Chemistry

IS - SUPPL. 1

ER -

Probing interactions bymeans of pulsed field gradient nuclear magnetic resonance spectroscopy

Abstract

Keywords

ASJC Scopus subject areas

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