TY - JOUR
T1 - New insights into the atomic structure of amorphous TiO2 using tight-binding molecular dynamics
AU - Yang, Kai
AU - Kachmar, Ali
AU - Wang, Bu
AU - Krishnan, N. M.Anoop
AU - Balonis, Magdalena
AU - Sant, Gaurav
AU - Bauchy, Mathieu
N1 - Publisher Copyright:
© 2018 Author(s).
PY - 2018/9/7
Y1 - 2018/9/7
N2 - Amorphous TiO2 (a-TiO2) could offer an attractive alternative to conventional crystalline TiO2 phases for photocatalytic applications. However, the atomic structure of a-TiO2 remains poorly understood with respect to that of its crystalline counterparts. Here, we conduct some classical molecular dynamics simulations of a-TiO2 based on a selection of empirical potentials. We show that, on account of its ability to dynamically assign the charge of each atom based on its local environment, the second-moment tight-binding charge equilibration potential yields an unprecedented agreement with available experimental data. Based on these simulations, we investigate the degree of order and disorder in a-TiO2. Overall, the results suggest that a-TiO2 features a large flexibility in its local topology, which may explain the high sensitivity of its structure to the synthesis method being used.
AB - Amorphous TiO2 (a-TiO2) could offer an attractive alternative to conventional crystalline TiO2 phases for photocatalytic applications. However, the atomic structure of a-TiO2 remains poorly understood with respect to that of its crystalline counterparts. Here, we conduct some classical molecular dynamics simulations of a-TiO2 based on a selection of empirical potentials. We show that, on account of its ability to dynamically assign the charge of each atom based on its local environment, the second-moment tight-binding charge equilibration potential yields an unprecedented agreement with available experimental data. Based on these simulations, we investigate the degree of order and disorder in a-TiO2. Overall, the results suggest that a-TiO2 features a large flexibility in its local topology, which may explain the high sensitivity of its structure to the synthesis method being used.
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U2 - 10.1063/1.5042783
DO - 10.1063/1.5042783
M3 - Article
C2 - 30195301
AN - SCOPUS:85052937241
SN - 0021-9606
VL - 149
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 9
M1 - 094501
ER -