Effect of zeolite pore morphology on solvent-less alkylation of benzene with 1-hexene

Sandeep K. Saxena, N. Viswanadham*, Ala'a H. Al-Muhtaseb

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)


In an attempt to convert the carcinogenic benzene which is almost restricted for its use in gasoline, alkylation reaction with olefin 1-hexene has been conducted on various zeolites. Four zeolites having different pore topology and pore size have been applied as solid acid catalysts for effective production of alkylate in a liquid phase, solvent-less low temperature reaction. The textural properties of all the four zeolites (ZSM-5, MOR, BEA, HY) have been characterized for crystal morphology by TEM, crystal structure by XRD and FTIR, BET for surface area, N2 sorption for porosity and TPD for acidity. Among the zeolite, BEA possessed high surface area (600.61 m2/g) and enhanced meso pores volume (0.3956 cm3/g) as compared to other zeolite samples. The performance of BEA was also observed to be superior in the liquid phase alkylation of benzene with 1-hexene in a batch reactor under autogenous pressure without using any solvent. At the optimum reaction conditions, the benzene conversion was 86.6 wt% and 3-Phenylhexane, 2-Phenylhexane yield were about 47.9 wt% and 38.7 wt% respectively on this catalyst. The BEA also exhibited longer time-on-stream and reusability performance, thus offers an attractive route for converting benzene into valuable (3-Phenylhexane, 2-Phenylhexane) alkylate product useful for the manufacturing of fine chemicals, dyestuff, detergents and scents.

Original languageEnglish
Pages (from-to)45-52
Number of pages8
JournalMaterials Today Chemistry
Publication statusPublished - Jun 2017


  • 1-hexene
  • Alkylation
  • Benzene
  • Mesopores
  • Pore volume
  • Zeolite

ASJC Scopus subject areas

  • Catalysis
  • Colloid and Surface Chemistry
  • Biomaterials
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics


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