TY - JOUR
T1 - Deep-level transient spectroscopy study of the E center in n-Si and partially relaxed n- Si0.9 Ge0.1 alloy layers
AU - Mamor, M.
AU - Elzain, M.
AU - Bouziane, K.
AU - Al Harthi, S. H.
PY - 2008/1/30
Y1 - 2008/1/30
N2 - We have employed deep-level transient spectroscopy to investigate the electronic properties of defects introduced during high energy He-ion irradiation of epitaxially grown phosphorous-doped n-Si and partially relaxed n- Si0.9 Ge0.1. It is found that He-ion irradiation introduces two major defects in Si and Si0.9 Ge0.1. These have been attributed to a doubly negative charge state of the divacancy (V2 = -) and V-P pair (E center). The germanium dependence of the activation enthalpy (EH) for both (V2 = -) and V-P pair is found to be relatively minute with a small decrease and increase in the corresponding EH with respect to that of Si, respectively. Comparison was made with earlier reported results in phosphorous-doped fully strained n- Si1-x Gex and antimony-doped totally relaxed n- Si1-x Gex layers to directly assess the influence of strain relaxation on radiation-related deep levels in Si1-x Gex. It is shown that the energy level of the V-P pair in fully strained and partially relaxed Si1-x Gex lies closely to that reported for V-Sb in fully relaxed Si1-x Gex. This result indicates that the V-P level is independent of strain, suggesting that such defect is pinned to the conduction band. Moreover, our calculation using full-potential linearized augmented plane wave method shows nonpreferential site occupancy of the phosphorous relative to Ge atoms. This implies a chemical disorder in the vicinity of the V-P center which leads to a fluctuation of the ionization energy level of the E center. This fluctuation is associated with a distribution of the electron emission rate between the V-P level and the conduction band edge.
AB - We have employed deep-level transient spectroscopy to investigate the electronic properties of defects introduced during high energy He-ion irradiation of epitaxially grown phosphorous-doped n-Si and partially relaxed n- Si0.9 Ge0.1. It is found that He-ion irradiation introduces two major defects in Si and Si0.9 Ge0.1. These have been attributed to a doubly negative charge state of the divacancy (V2 = -) and V-P pair (E center). The germanium dependence of the activation enthalpy (EH) for both (V2 = -) and V-P pair is found to be relatively minute with a small decrease and increase in the corresponding EH with respect to that of Si, respectively. Comparison was made with earlier reported results in phosphorous-doped fully strained n- Si1-x Gex and antimony-doped totally relaxed n- Si1-x Gex layers to directly assess the influence of strain relaxation on radiation-related deep levels in Si1-x Gex. It is shown that the energy level of the V-P pair in fully strained and partially relaxed Si1-x Gex lies closely to that reported for V-Sb in fully relaxed Si1-x Gex. This result indicates that the V-P level is independent of strain, suggesting that such defect is pinned to the conduction band. Moreover, our calculation using full-potential linearized augmented plane wave method shows nonpreferential site occupancy of the phosphorous relative to Ge atoms. This implies a chemical disorder in the vicinity of the V-P center which leads to a fluctuation of the ionization energy level of the E center. This fluctuation is associated with a distribution of the electron emission rate between the V-P level and the conduction band edge.
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U2 - 10.1103/PhysRevB.77.035213
DO - 10.1103/PhysRevB.77.035213
M3 - Article
AN - SCOPUS:38849174298
SN - 1098-0121
VL - 77
JO - Physical Review B - Condensed Matter and Materials Physics
JF - Physical Review B - Condensed Matter and Materials Physics
IS - 3
M1 - 035213
ER -