Biodiesel production by valorizing waste Phoenix dactylifera L. Kernel oil in the presence of synthesized heterogeneous metallic oxide catalyst (Mn@MgO-ZrO2)

Farrukh Jamil; Ala'a H. Al-Muhatseb; Myo Tay Zar Myint; Mohab Al-Hinai; Lamya Al-Haj; Mahad Baawain; Mohammed Al-Abri; Gopalakrishnan Kumar; A. E. Atabani

doi:10.1016/j.enconman.2017.10.064

Biodiesel production by valorizing waste Phoenix dactylifera L. Kernel oil in the presence of synthesized heterogeneous metallic oxide catalyst (Mn@MgO-ZrO₂)

Farrukh Jamil, Ala'a H. Al-Muhatseb^*, Myo Tay Zar Myint, Mohab Al-Hinai, Lamya Al-Haj, Mahad Baawain, Mohammed Al-Abri, Gopalakrishnan Kumar, A. E. Atabani

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

95 Citations (Scopus)

Abstract

The present study intended to produce biodiesel as an efficient fuel from waste Phoenix dactylifera L. kernel oil in the presence of synthesized efficient heterogeneous metallic oxide catalyst (Mn@MgO-ZrO₂). The performance of synthesized metallic oxide catalyst was evaluated based on biodiesel yield and the process has been optimized. The optimum biodiesel yield was 96.4%, when process temperature was 90 °C, catalyst loading 3 wt%, methanol to oil ratio 15:1 and reaction duration was 4 h. The product biodiesel was characterized in order to evaluate its quality according to ASTM and EN standards. Thus, characterization of biodiesel revealed that it fulfills the standard ranges defined by ASTM and EN: its acid value was 0.11 mg KOH/g, density 881 kg/m³, viscosity 3.85 mm²/s, flash point 142 °C and suitable low-temperature properties. It can thus be concluded that synthesized heterogeneous catalyst can be used efficiently for biodiesel production from waste Phoenix dactylifera L. kernel oil which satisfied the international standards defined by ASTM and EN.

Original language	English
Pages (from-to)	128-137
Number of pages	10
Journal	Energy Conversion and Management
Volume	155
DOIs	https://doi.org/10.1016/j.enconman.2017.10.064
Publication status	Published - Jan 1 2018

Keywords

Biodiesel
Esterification
Heterogeneous metallic oxide catalyst
Transesterification
Waste Phoenix dactylifera L. kernel oil

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Nuclear Energy and Engineering
Fuel Technology
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.enconman.2017.10.064

Cite this

Jamil, F., Al-Muhatseb, A. H., Myint, M. T. Z., Al-Hinai, M., Al-Haj, L., Baawain, M., Al-Abri, M., Kumar, G., & Atabani, A. E. (2018). Biodiesel production by valorizing waste Phoenix dactylifera L. Kernel oil in the presence of synthesized heterogeneous metallic oxide catalyst (Mn@MgO-ZrO₂). Energy Conversion and Management, 155, 128-137. https://doi.org/10.1016/j.enconman.2017.10.064

Jamil, F, Al-Muhatseb, AH , Myint, MTZ, Al-Hinai, M, Al-Haj, L, Baawain, M, Al-Abri, M, Kumar, G & Atabani, AE 2018, 'Biodiesel production by valorizing waste Phoenix dactylifera L. Kernel oil in the presence of synthesized heterogeneous metallic oxide catalyst (Mn@MgO-ZrO₂)', Energy Conversion and Management, vol. 155, pp. 128-137. https://doi.org/10.1016/j.enconman.2017.10.064

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abstract = "The present study intended to produce biodiesel as an efficient fuel from waste Phoenix dactylifera L. kernel oil in the presence of synthesized efficient heterogeneous metallic oxide catalyst (Mn@MgO-ZrO2). The performance of synthesized metallic oxide catalyst was evaluated based on biodiesel yield and the process has been optimized. The optimum biodiesel yield was 96.4%, when process temperature was 90 °C, catalyst loading 3 wt%, methanol to oil ratio 15:1 and reaction duration was 4 h. The product biodiesel was characterized in order to evaluate its quality according to ASTM and EN standards. Thus, characterization of biodiesel revealed that it fulfills the standard ranges defined by ASTM and EN: its acid value was 0.11 mg KOH/g, density 881 kg/m3, viscosity 3.85 mm2/s, flash point 142 °C and suitable low-temperature properties. It can thus be concluded that synthesized heterogeneous catalyst can be used efficiently for biodiesel production from waste Phoenix dactylifera L. kernel oil which satisfied the international standards defined by ASTM and EN.",

keywords = "Biodiesel, Esterification, Heterogeneous metallic oxide catalyst, Transesterification, Waste Phoenix dactylifera L. kernel oil",

author = "Farrukh Jamil and Al-Muhatseb, {Ala'a H.} and Myint, {Myo Tay Zar} and Mohab Al-Hinai and Lamya Al-Haj and Mahad Baawain and Mohammed Al-Abri and Gopalakrishnan Kumar and Atabani, {A. E.}",

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AU - Al-Muhatseb, Ala'a H.

AU - Myint, Myo Tay Zar

AU - Al-Hinai, Mohab

AU - Al-Haj, Lamya

AU - Baawain, Mahad

AU - Al-Abri, Mohammed

AU - Kumar, Gopalakrishnan

AU - Atabani, A. E.

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N2 - The present study intended to produce biodiesel as an efficient fuel from waste Phoenix dactylifera L. kernel oil in the presence of synthesized efficient heterogeneous metallic oxide catalyst (Mn@MgO-ZrO2). The performance of synthesized metallic oxide catalyst was evaluated based on biodiesel yield and the process has been optimized. The optimum biodiesel yield was 96.4%, when process temperature was 90 °C, catalyst loading 3 wt%, methanol to oil ratio 15:1 and reaction duration was 4 h. The product biodiesel was characterized in order to evaluate its quality according to ASTM and EN standards. Thus, characterization of biodiesel revealed that it fulfills the standard ranges defined by ASTM and EN: its acid value was 0.11 mg KOH/g, density 881 kg/m3, viscosity 3.85 mm2/s, flash point 142 °C and suitable low-temperature properties. It can thus be concluded that synthesized heterogeneous catalyst can be used efficiently for biodiesel production from waste Phoenix dactylifera L. kernel oil which satisfied the international standards defined by ASTM and EN.

AB - The present study intended to produce biodiesel as an efficient fuel from waste Phoenix dactylifera L. kernel oil in the presence of synthesized efficient heterogeneous metallic oxide catalyst (Mn@MgO-ZrO2). The performance of synthesized metallic oxide catalyst was evaluated based on biodiesel yield and the process has been optimized. The optimum biodiesel yield was 96.4%, when process temperature was 90 °C, catalyst loading 3 wt%, methanol to oil ratio 15:1 and reaction duration was 4 h. The product biodiesel was characterized in order to evaluate its quality according to ASTM and EN standards. Thus, characterization of biodiesel revealed that it fulfills the standard ranges defined by ASTM and EN: its acid value was 0.11 mg KOH/g, density 881 kg/m3, viscosity 3.85 mm2/s, flash point 142 °C and suitable low-temperature properties. It can thus be concluded that synthesized heterogeneous catalyst can be used efficiently for biodiesel production from waste Phoenix dactylifera L. kernel oil which satisfied the international standards defined by ASTM and EN.

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