ملخص
The novel azoimine ligand α-acetyl-α-phenylazo-4-chlorophenylazomethine (L) was prepared and characterized. Its coordination chemistry to Ru(II) was investigated by the preparation and characterization of the complex trans-[Ru(bpy)LCl2] where bpy is 2,2′-bipyridine. A crystal structure of this complex showed that L is a bidentate ligand and coordinates to Ru(II) by azo-and imine-nitrogen donor atoms. Cyclic voltammetry and spectroelectrochemistry were performed on this complex and the visible region absorption bands assigned. L is shown to be a strong π-acid ligand.
اللغة الأصلية | English |
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الصفحات (من إلى) | 2395-2399 |
عدد الصفحات | 5 |
دورية | Inorganica Chimica Acta |
مستوى الصوت | 359 |
رقم الإصدار | 8 |
المعرِّفات الرقمية للأشياء | |
حالة النشر | Published - مايو 15 2006 |
منشور خارجيًا | نعم |
ASJC Scopus subject areas
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