TY - JOUR
T1 - N,N-Dimethyl-5-methoxymethyl-2′-deoxycytidine
AU - Audette, Gerald F.
AU - Zoghaib, Wajdi M.
AU - Gupta, Sagar V.
AU - Quail, J. Wilson
AU - Delbaere, Louis T.J.
PY - 1999/3/15
Y1 - 1999/3/15
N2 - In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [ χ = 193.54 (19)°]. The deoxyribose sugar ring has the C2′-exo-C3′-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2)° and τm = 38.27 (2)°. The exocyclic side chain at C5′ has the g+ conformation [γ = 47.7 (3)°]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3)°.
AB - In the title compound, C13H21N3O5, the pyrimidine ring adopts the antiperiplanar (-ap) conformation [ χ = 193.54 (19)°]. The deoxyribose sugar ring has the C2′-exo-C3′-endo (2T3) twist conformation. The pseudo-rotational parameters of the deoxyribose sugar ring are P = 6.83 (2)° and τm = 38.27 (2)°. The exocyclic side chain at C5′ has the g+ conformation [γ = 47.7 (3)°]. The 5-methoxymethyl group is distal to the deoxyribose sugar ring, with a C6-C5-C52-O52 torsion angle of -91.9 (3)°.
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U2 - 10.1107/S0108270198013249
DO - 10.1107/S0108270198013249
M3 - Article
C2 - 10220872
AN - SCOPUS:0346965708
SN - 0108-2701
VL - 55
SP - 427
EP - 430
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 3
ER -