TY - JOUR
T1 - Biogenic synthesis of palladium nanoparticles with Albizia gum for degradation of Congo red and 4-nitrophenol dyes
AU - Al Khazaleh, Mahmoud
AU - Bhagavanth Reddy, G.
AU - Al-Abri, Mohammed
AU - Seku, Kondaiah
N1 - Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2023/8/1
Y1 - 2023/8/1
N2 - A microwave technique was used to prepare palladium nanoparticles (PdNPs) from albizia gum (AG). A major advantage of this method is its rapidity, low cost, and no toxic chemicals. UV–Visible spectrophotometer, FTIR, powder XRD, and TEM were employed to characterize the synthesized AG@PdNPs. The XRD spectrum confirmed a face-centred cubic structure for PdNPs. A spherical shape and 12–14 nm diameter were observed in TEM images of AG@PdNPs. AG@PdNPs effectively degraded Congo red (CR) and 4-nitrophenol (4-NP) dyes in the presence of NaBH4. These reduction processes were explored using a pseudo-first-order kinetic analysis. The impact of temperature and dosage of catalyst on the degradation of 4-nitrophenol to 4-aminophenol was examined. In addition to other thermodynamic properties like activation enthalpy and entropy, the activation energy was estimated. The recyclability of AG@PdNPs was also assessed. AG@PdNPs have a high potential as an environmental catalyst for water remediation.
AB - A microwave technique was used to prepare palladium nanoparticles (PdNPs) from albizia gum (AG). A major advantage of this method is its rapidity, low cost, and no toxic chemicals. UV–Visible spectrophotometer, FTIR, powder XRD, and TEM were employed to characterize the synthesized AG@PdNPs. The XRD spectrum confirmed a face-centred cubic structure for PdNPs. A spherical shape and 12–14 nm diameter were observed in TEM images of AG@PdNPs. AG@PdNPs effectively degraded Congo red (CR) and 4-nitrophenol (4-NP) dyes in the presence of NaBH4. These reduction processes were explored using a pseudo-first-order kinetic analysis. The impact of temperature and dosage of catalyst on the degradation of 4-nitrophenol to 4-aminophenol was examined. In addition to other thermodynamic properties like activation enthalpy and entropy, the activation energy was estimated. The recyclability of AG@PdNPs was also assessed. AG@PdNPs have a high potential as an environmental catalyst for water remediation.
KW - Activation of entropy and enthalpy changes
KW - Albizia gum
KW - Catalytic activity
KW - Palladium nanoparticles
KW - Reusability of catalyst
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UR - https://www.mendeley.com/catalogue/500c02c9-9bc5-3e6f-8cfe-3f2126012d64/
U2 - 10.1016/j.optmat.2023.113970
DO - 10.1016/j.optmat.2023.113970
M3 - Article
AN - SCOPUS:85161559078
SN - 0925-3467
VL - 142
JO - Optical Materials
JF - Optical Materials
M1 - 113970
ER -