Aggregation behavior of sugar surfactants in aqueous solutions: Effects of temperature and the addition of nonionic polymers

Mohamed Aoudia, Raoul Zana*

*المؤلف المقابل لهذا العمل

نتاج البحث: المساهمة في مجلةArticleمراجعة النظراء

88 اقتباسات (Scopus)


The aggregation behavior, critical micelle concentration (cmc) and micelle aggregation number (N), of dodecyl maltoside (DM), octyl glucoside (OG), and Hecameg has been investigated in water and in water plus one of the three water-soluble polymers, polyoxyethylene (POE), polyoxypropylene (POP), and polyvinyl pyrrolidone (PVP), by means of florescence probing and time- resolved fluorescence quenching. The cmc of DM in water increased with temperature and showed a slight increase in the presence of POE. The aggregation number N of DM micelles was nearly independent of concentration (0.25-1 wt %) and temperature (16-60°C). It remained invariant upon addition of 2 wt % POE or PVP but decreased slightly upon addition of the more hydrophobic POP. With increasing temperature, the cmc of OG decreased, went through a shallow minimum at around 35°C, and increased. Addition of POE slightly increased the cmc in the whole temperature range. The aggregation number of OG micelles showed a fairly flat maximum at around 30°C, and was unaffected by the presence of 2 wt % POE or PVP. However, N showed a complex dependence on temperature in the presence of POP, with lower values than in pure water below 15°C, and rapidly increasing quencher-dependent values above this temperature. Hecameg was characterized by N-values nearly independent of temperature and concentration. Intermicellar exchanges of probe and/or quencher were observed with OG and Hecameg, but not with DM. The above results are compared to those for the nonionic ethoxylated surfactants. The effect of various parameters on the micelle aggregation number, the micelle polydispersity, the occurrence of sugar surfactant/nonionic polymer interactions, and the mechanisms responsible for the observed intermicellar exchanges are discussed.

اللغة الأصليةEnglish
الصفحات (من إلى)158-167
عدد الصفحات10
دوريةJournal of Colloid and Interface Science
مستوى الصوت206
رقم الإصدار1
المعرِّفات الرقمية للأشياء
حالة النشرPublished - أكتوبر 1 1998

ASJC Scopus subject areas

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