TY - CHAP
T1 - 2.15 Selected Diastereoselective Reactions
T2 - Substrate Controlled Stereoselective Conjugate Addition Reactions with Organocopper Reagents
AU - Siengalewicz, P.
AU - Mulzer, J.
AU - Rinner, U.
PY - 2012/9
Y1 - 2012/9
N2 - The importance of conjugate addition reactions with organocopper reagents has increased since the seminal synthetic application, as reported by Robinson in the early 1940s. This review chapter is intended to provide an overview of substrate-controlled diastereoselective conjugate organocuprate addition reactions, utilized in the preparation of complex natural products on selected syntheses which have been published within the past decade.
AB - The importance of conjugate addition reactions with organocopper reagents has increased since the seminal synthetic application, as reported by Robinson in the early 1940s. This review chapter is intended to provide an overview of substrate-controlled diastereoselective conjugate organocuprate addition reactions, utilized in the preparation of complex natural products on selected syntheses which have been published within the past decade.
KW - Complex natural products
KW - Diastereoselective conjugate organocuprate addition reactions
KW - Organocopper reagents
UR - http://www.scopus.com/inward/record.url?scp=84902425239&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84902425239&partnerID=8YFLogxK
U2 - 10.1016/B978-0-08-095167-6.00225-1
DO - 10.1016/B978-0-08-095167-6.00225-1
M3 - Chapter
AN - SCOPUS:84902425239
SN - 9780080951683
VL - 2
SP - 441
EP - 471
BT - Synthetic Methods I - Chiral Pool and Diastereoselective Methods
PB - Elsevier Ltd
ER -